There are a few products on the market that help minimise tear stains. I have had success with a product called "Angels Eyes" on my cavoodle. It is a powdered supplement that is added to your dogs food that neutralises the tear stains. You can read more about it and purchase it here;
http://www.angelseyesaustralia.com
They tell you to allow 6-8 weeks for it to be noticeable, but after just 1 week you can see the difference in Lulu.
There are also an assortment of whipes, sprays, creams etc that may help, but it's might be worthwhile to shop around with what works for you.
The cause of tear staining is so varied, it could be a breeding problem causing a deformity in the tear ducts, allergies or diet. Most commonly the problem is usually associated with bad diet. Most supermarket foods contain artificial colors, preservatives etc, which end up coming out through the dogs skin, saliva etc. Have you ever wondered why your pretty white dog ends up with red/pink patches, usually on their feet and base of tail? That's the same enzymes as the tear staining.
At the end of the day if you just keep that area clean you should have minimal problems.
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